Diacetone-D-glucose Chemical Properties |
Melting point | 110-111 °C(lit.) |
alpha | -11 º (c=5, EtOH) |
Boiling point | 323.54°C (rough estimate) |
density | 1.1432 (rough estimate) |
refractive index | -18.5 ° (C=5, H2O) |
storage temp. | Inert atmosphere,Store in freezer, under -20°C |
form | Powder |
pka | 13.15±0.60(Predicted) |
color | White to yellow |
optical activity | [α]20/D 18°, c = 1% in H2O |
Water Solubility | slightly soluble |
Merck | 14,2965 |
BRN | 84386 |
InChIKey | KEJGAYKWRDILTF-YENDLIOYSA-N |
EPA Substance Registry System | Diacetone glucose (582-52-5) |
Safety Information |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 24/25-36/37-26 |
WGK Germany | 2 |
RTECS | LZ4958000 |
F | 3-10 |
TSCA | Yes |
HS Code | 29329970 |
Toxicity | LD50 oral in mouse: 4gm/kg |
Diacetone-D-glucose Usage And Synthesis |
Chemical Properties | white to light yellow crystal powde |
Purification Methods | Diacetone-D-glucose crystallises from Et2O, (needles), pet ether or *C6H6 and sublimes in vacuo. It is soluble in 7 volumes of H2O and 200 volumes of pet ether at their boiling points. The solubility in H2O at 17.5o is 4.3%. It precipitates from aqueous solutions on basification with NaOH. [Schmid & Karrer Helv Chim Acta 32 1371 1949, Fischer & Rund Chem Ber 49 90, 93 1916, IR: Kuhn Anal Chem 22 276 1950, Beilstein 19/12 V 318.] |